It appears that there is certainly some kind of chemistry between the two characters in both clips. In the canoe clip, it is he that is wanting to be noticed in a good way through his song that is meant to impress her. She is obviously smitten by the gesture even though she playfully mocks him about it. In the saloon scene, once she notices him arrive, she then takes the role of wanting to be "noticed" in a good way by him, although her attempt also fails, he is definitely smitten with her as well.
